Download PDF by Ernest L. Eliel: Asymmetric Reactions and Processes in Chemistry

By Ernest L. Eliel

ISBN-10: 0841207178

ISBN-13: 9780841207172

ISBN-10: 0841208786

ISBN-13: 9780841208780

content material: ways for uneven synthesis as directed towards typical items / Barry M. Trost --
man made regulate resulting in normal items / Teruaki Mukaiyama --
uneven synthesis of chiral tertiary alcohols in excessive enantiomeric extra / Ernest L. Eliel, Jorma ok. Koskimies, Bruno Lohri, W. Jack Frazee, Susan Morris-Natschke, Joseph E. Lynch, and Kenso Soai --
Acyclic stereoselection through the aldol condensation / Clayton H. Heathcock --
uneven carbon-carbon bond forming reactions through chiral chelated intermediates : diastereoselective uneven synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes / Kenji Koga --
uneven carbon-carbon bond forming reactions through chiral oxazolines / Albert I. Meyers --
hugely selective synthesis with novel metal reagents / Hitosi Nozaki, Tamejiro Hiyama, Koichiro Oshima, and Kazuhiko Takai --
Novel methods to the uneven synthesis of peptides / Iwao Ojima --
uneven carbon-carbon bond formation utilizing enantiomerically natural vinylic sulfoxides / Gary H. Posner, John P. Mallamo, Kyo Miura, and Martin Hulce --
uneven reactions : a problem to the commercial chemist / Gabriel Saucy and Noal Cohen --
Stereochemistry of heterogeneous uneven catalytic hydrogenation / Kaoru Harada --
uneven Grignard cross-coupling catalyzed through chiral phosphine-nickel and phosphine-palladium complexes / Tamio Hayashi --
Rhodium(I) catalyzed enantioselective hydrogen migration of prochiral allylamines / okay. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita, and R. Noyori --
software of immobilized enzymes for uneven reactions / Ichiro Chibata --
uneven synthesis utilizing cofactor-requiring enzymes / George M. Whitesides, Chi-Huey Wong, and Alfred Pollak --
Mechanistic issues of biomimetic uneven savings / Atsuyoshi Ohno --
Stereochemistry of one-carbon move reactions / Heinz G. Floss --
an invaluable and with ease available chiral desk bound part for the liquid chromatographic separation of enantiomers / William H. Pirkle, John M. Finn, Bruce C. impede, James Schreiner, and James R. Pribish --
New uneven reactions utilizing (S)-2-aminomethylpyrrolidine derivatives / Masatoshi Asami --
Liquid chromatographic answer of enantiomeric [alpha]-amino acid derivatives applying a chiral diamide part / Shoji Hara, Akira Dobashi, and Masakatzu Eguchi --
uneven aid with chiral NADH version compounds / Yuzo Inouye --
uneven hydrogenation of cyclic dipeptides containing [alpha], [beta]-dehydroamino acid residues and next education of optically natural [alpha]-amino acids / Nobuo Izumiya.

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Extra resources for Asymmetric Reactions and Processes in Chemistry

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E) Alkylmagnesium i o d i d e s are m a r g i n a l l y s u p e r i o r t o alkylmagnesium bromides which are a p p r e c i a b l y b e t t e r than alkylmagnesium c h l o r i d e s . T h i s order came as somewhat o f a s u r p r i s e s i n c e we had expected the c h l o r i d e s to be b e t t e r c o o r d i n a t i n g s p e c i e s . E a r l i e r l i t e r a t u r e on t h i s p a r t i c u l a r l y p o i n t (13) i s not c l e a r - c u t . f ) In some i n s t a n c e s , a mixture o f ether and t e t r a h y d r o f u r a n i s s u p e r i o r t o d i e t h y l ether i t s e l f , but the e f f e c t i s m a r g i n a l .

Tramontini, M. -P. E. Soc. H. Tetrahedron Lett. 1980, 1031 and refs. there cited. 14. Dissertation, University of North Carolina, Chapel Hill, NC, 1981. 15. S. Soc. 1949, 3098. 16. ; Allenmark, S. Scripta 1974, 5, 13. 17. cf. W. "Protective Groups in Organic Synthesis"; Wiley-Interscience: New York, 1981; pp. 133-140. 18. ; Ogasawara, K. Chem. Commun. ; Jurion, M. ibid. 1972, 382. 19. -i. Bull. 1975, 23, 527. 20. J. Chem. 1979, 44, 3598. 21. E. Tetrahedron Lett. 1981, 22, 2855. 22. L. unpublished observations.

Unpublished observations. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 3. ELIEL ET AL. ch003 23. 24. 25. 26. L. unpublished observations. ; Soai, K. Tetrahedron Lett. 1981, 22, 2859. W. Chem. 1971, 36, 3553. ; Konno, K. (London) 1964, 233. 27. Regarding previous reports on chiral 10a and 10b, cf. J. Chem. H. Soc. 1951, 73, 2391. 28. ; Asami, M. Lett. 1978, 1253; 1979, 705. 29. J. Tetrahedron Lett. D. Synthesis 1970, 466. 30. ; Rich, P. (C) 1968, 1693. 31. cf. S. ; Schreiner, J .

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Asymmetric Reactions and Processes in Chemistry by Ernest L. Eliel

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