By Teresa S. Bowers, Kenneth J. Jackson, Prof. Harold C. Helgeson (auth.)
This ebook represents a revision and enlargement of an previous set of diagrams for tempera zero zero tures from 25 to three hundred C alongside the equilibrium vapor-liquid curve for H zero (Helgeson, Brown, 2 and Leeper, 1969). The task diagrams summarized within the following pages have been generated over a six 12 months interval from 1977 to 1983 within the Laboratory of Theoretical Geochemistry (oth erwise referred to as Prediction Centra!) on the collage of California, Berkeley. They characterize the fruits of analysis efforts to generate a accomplished and internally constant set of thermodynamic info and equations for minerals, gases, and aqueous strategies at excessive pres sures and temperatures. one of the who contributed to the winning crowning glory of this ebook, we're in particular indebted to David Kirkham, John Walther, and George vegetation, who wrote application SUPCRT, Tom Brown, who created application DIAGRAM, and Eli Mess inger, who generated the Tektronix plot regimen to build the diagrams. Ken Jackson and Terri Bowers either dedicated an important period of time and energy during the last six years to supply the diagrams within the following pages; a few of which went via many levels of revision. therefore, they seem as senior authors of this quantity. it may be pointed out during this regard that their equivalent commitment to the venture made it essential to make certain their order of authorship by way of flipping a coin.
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Additional resources for Equilibrium Activity Diagrams: For Coexisting Minerals and Aqueous Solutions at Pressures and Temperatures to 5 kb and 600 °C
13 e. ) PER ~ 3-27 . ~ ":-~--=-~:--:-~::-' -6. 13 -4. 0 13 . 13 LOG CACSI02CAQ») Phase relations in the system HCI-H 20-AI 20 3 -(MgO)-Si0 2• Metastable chrysotile was considered instead of its stable counterpart, antigorite. Saturation limits: quartz (a), amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), andalusite (f), kyanite (g), sillimanite (h), kaolinite (i), pyrophyllite (j). 24 '" 17. 0 :;;! 0 SPI~~~ \~i:FO~D / \ \. 0 + + :;;! ) ~ '" <;> '"* \ 11 I I 7-~\q. \ -c- I I I ) I N t Lc BRUC HRY I I ~\ r 5.
0 :I: v ~ ~ ,3 . 0 v ~ I SPTNEL \ ? 0 + . 0 -3. 0 0. 0 LOG CACSI02CAQ))) ,. \ I 1 J'b I. 0 * 1 1 ~ ~ ,... ~ I I ,. 0 v' \\ I I ~ ~- l. + ;;i v 2 0 ~. 0 -3. 0 0. 0 LOG CACSI02CAQ))) v v * ~ 3. 0 + :I: "~ 4. 0 ,... 0 ,... "~ 9. 0 1. 0 LOG CACSI02CAQ))) ,... , ~3. 0 SPINEL v"'''' ~ ~ "'. 0 LOG CACSI02CAQ))) Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si0 2• Metastable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Saturation limits: quartz (a), amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), andalusite (f), kyanite (g), sillimanite (h), kaolinite (i), pyrophyllite (j).
284 (in press). , 1984, Activity/composition relations among silicates and aqueous sohitions. I. Thermodynamics of intrasite mixing and substitutional order/disorder in minerals: Am. Jour. , v. 284 (in press). , 253 p. , 1970, Calculation of mass transfer in geochemical processes involving aqueous solutions: Geochim. et Cosmochim . Acta, v. 34, p. 569-592. , 1978, Summary and critique of the thermodynamic properties of rock-forming minerals: Am. Jour. , v. 278-A, p. 1229. , 1969, Evaluation of irreversible reactions in geochemical processes involving minerals and aqueous solutions--II.
Equilibrium Activity Diagrams: For Coexisting Minerals and Aqueous Solutions at Pressures and Temperatures to 5 kb and 600 °C by Teresa S. Bowers, Kenneth J. Jackson, Prof. Harold C. Helgeson (auth.)