Read e-book online Polymer Thermodynamics: Liquid Polymer-Containing Mixtures PDF

By Bernhard A. Wolf (auth.), Bernhard A. Wolf, Sabine Enders (eds.)

ISBN-10: 364217681X

ISBN-13: 9783642176814

Making Flory-Huggins functional: Thermodynamics of Polymer-Containing combos, through B. A. Wolf
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Aqueous ideas of Polyelectrolytes: Vapor-Liquid Equilibrium and a few similar homes, by means of G. Maurer, S. Lammertz, and L. Ninni Schäfer
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Gas-Polymer Interactions: Key Thermodynamic info and Thermophysical houses, through J.-P. E. Grolier, and S. A.E. Boyer
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Interfacial stress in Binary Polymer Blends and the results of Copolymers as Emulsifying brokers, via S. H. Anastasiadis
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Theory of Random Copolymer Fractionation in Columns, by means of Sabine Enders
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Computer Simulations and Coarse-Grained Molecular versions Predicting the Equation of nation of Polymer recommendations, by means of ok. Binder, B. Mognetti, W. Paul, P. Virnau, and L. Yelash
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Modeling of Polymer section Equilibria utilizing Equations of nation, by means of G. Sadowski

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Extra info for Polymer Thermodynamics: Liquid Polymer-Containing Mixtures

Example text

According to [32], the crossed squares refer to compositions inside the range of glassy solidification; no information is given for the open squares. 0 HS-GC PS HS–GC as usual and another set [32] obtained by means of the so-called “flow through” method, which differs fundamentally. The vapor pressure data obtained by means of HS–GC measurements for the solutions of PS (below the glass transition temperature of the polymer) in the favorable solvent TL resemble closely the results for the solutions of polyethylene oxide (PEO) in chloroform (below the melting temperature of the polymer), as shown later.

0 PEO Thermodynamics of Polymer-Containing Mixtures 37 the attainment of equilibria. Range II assumes an intermediate position in this respect. , in the course of solvent removal or quenching of the polymer melt. For discussion of these effects it is helpful to compare the fraction of the polymer that does not participate in the liquid/vapor equilibrium with the degree of crystallinity as obtained from DSC measurements. The general findings that the former is always larger than the latter, and that the differences decrease upon dilution, are tentatively interpreted as a trapping of amorphous PEO inside the crystalline material during sample preparation and its gradual release by the addition of solvent.

For all systems under investigation, ww varies considerably with the composition of the mixture. 5] the dependencies ww(w) of the copolymers do not fall reasonably between the data obtained for the corresponding homopolymers. In most cases, the incorporation of a small fraction [25] of the monomer that interacts less favorably with a given solvent suffices to reduce the solvent quality for the copolymer, approximately to that for the worse soluble homopolymer. Figure 14 shows an example for which this effect is particularly obvious.

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Polymer Thermodynamics: Liquid Polymer-Containing Mixtures by Bernhard A. Wolf (auth.), Bernhard A. Wolf, Sabine Enders (eds.)


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