Download e-book for iPad: Pulse and Fourier Transform NMR. Introduction to Theory and by Thomas C. Farrar

By Thomas C. Farrar

ISBN-10: 0122496507

ISBN-13: 9780122496509

Pulse and Fourier rework NMR: advent to idea and techniques provides the differing kinds of pulse experiments which are familiar and offers the theoretical history valuable for knowing those strategies. This e-book evaluates the sensible software of pulse tools and the mandatory instrumentation. prepared into seven chapters, this publication starts off with an outline of the NMR basics and the fundamental pulse equipment. this article then summarizes the real positive factors of pulse spectrometers. different chapters ponder the explanation, the benefits, and the constraints of Fourier remodel NMR equipment. This ebook discusses besides how the assumption of the rotating body can be used to appreciate sure experiments that reach the variety of program of pulse tools. the ultimate bankruptcy bargains with a number of major targeted makes use of of pulse recommendations. This booklet is a necessary source for chemists and readers who're accustomed to excessive answer NMR yet with out heritage in pulse tools.

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Extra info for Pulse and Fourier Transform NMR. Introduction to Theory and Methods

Example text

3. 2 is recast into t h e form In ( A . 3) where A is t h e initial amplitude of t h e F I D following t h e 90° pulse a t t i m e r, and A* is t h e limiting value of A for a very long interval between t h e 180° and 90° pulses. Ti is determined from t h e slope of a plot of In (A « — A ) VS. r. βθΓι. T h u s T\ can be found from t h e pulse spacing r t h a t results in no free induction signal following t h e 90° pulse. While useful for a rough measure­ ment, this procedure is inadequate for accurate determination of 7 \ , as we shall see when we consider some of t h e i n s t r u m e n t a l requirements in C h a p t e r 3.

Viewed from t h e laboratory frame, Μ is precessing at a r a t e o>o = 7 # o a b o u t t h e ζ axis. 5. As we shall see in more detail later, Μ relaxes because of t h e interaction with t h e microscopic magnetic m o m e n t s of t h e nuclear spins. As t h e molecules move a b o u t in space they, of course, carry t h e nuclear spins with t h e m and t h e motions of t h e nuclear magnetic m o m e n t s generate fluctuating magnetic fields. These microscopic fluctuating fields, which we denote b y h, behave in m a n y respects like t h e H i field generated in an N M R transmitter.

F o r example, field/frequency drift can seriously alter results obtained b y t h e C P M G techniques as we point out in C h a p t e r s 3 and 7. 6 F o u r i e r T r a n s f o r m M e t h o d s W e h a v e seen t h a t a nuclear spin system t h a t shows only a single Lorentzian line in t h e frequency sweep of a n ordinary N M R s p e c t r u m gives a simple exponential decay of t h e free induction following a 90° pulse. I t is well k n o w n t h a t a n exponential in t h e time domain and a Lorentzian in t h e frequency domain are Fourier transforms of each other.

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Pulse and Fourier Transform NMR. Introduction to Theory and Methods by Thomas C. Farrar


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