Quantitative chemical analysis solution manual by Daniel C. Harris PDF

By Daniel C. Harris

ISBN-10: 1429231238

ISBN-13: 9781429231237

This handbook presents entire, step by step, worked-out options for all difficulties and routines broadly speaking textual content, permitting scholars to study and additional improve their method of them.

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6-23. (a) BF3 (b) AsF5 6-24. 096 M Chemical Equilibrium 6-25. « x 10-3 M [ZnOH+] - p|[Zn2+] [OH"] = ßiA-sp/[OH-] = 9 x 10"« M [ZníOH)^)] = ß2[Zn2+] [OH]2 = p3ATsp [OH] = 6x lO^M [Zn(OH)"] = p3[Zn2+] [OH"]3 = ß3A:sp[OH"] = 8 x 10-9 M [Zn(OH)24] = ß4[Zn2+] [OH7» = ß^sp [OH"]2 = 9 x lfr«4 M Na+ + 6-26. 15. ). 6-27. ) 6-28. 1 x lO"5 = [Pbl2(aq)] Lewis acids and bases are electron pair acceptors and donors, respectively: + F3B + :Ö(CH3)2 -> Lewis Lewis acid base F3B-Ö(CH3)2 . , Adduct Br0nsted acids and bases arc proton donors and acceptors, respectively: 1I2S + ^ 5 N : -* < 0 N H + + HS Bronsted Branstcd acid base 6-29.

The pressure of reactant and product both increase by a factor of 8. However, reactant appears to the second power in the reaction quotient and product only appears to the first power. Increasing each pressure by the same factor decreases the reaction quotient. (e) Smaller. An exothermic reaction liberates heat. Adding heat is like adding a product. 53 54 Chapter 6 (a) ä - = / > H 2 0 = e-AG°/Ä7,= e-iAH° - TAS°yRT 6-10. 7 x lO^bar (b) Pn20 - 1 • e-iW°-T*S°y/tT => AH° - TAS° must be zero. AIP A/T - TAS° = O => T = — = 426 K = 153°C 6-11.

Criteria: • Observations outside action lines — no • 2 out of 3 consecutive measurements between warning and action lines — no 41 Quality Assurance and Calibration Methods • 7 consecutive measurements all above or all below the center line — YES: observations 2-10 (starting from the left side) are all below the center line • 6 consecutive measurements steadily increasing or steadily decreasing — no • 14 consecutive points alternating up and down — no • Obvious nonrandom pattern — no 5-15. LINEST gives m, b, sm, s^ Ä2, and sy in cells B19:C21.

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